[1]农韦健 胡雪玲 陈小鹏 韦小凤 容建峰.固-液相平衡测定与关联[J].大众科技,2020,22(09):46-48.
 Measurement and Correlation of Solid–Liquid Equilibrium[J].Popular Science & Technology,2020,22(09):46-48.
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固-液相平衡测定与关联()
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《大众科技》[ISSN:1008-1151/CN:45-1235/N]

卷:
22
期数:
2020年09
页码:
46-48
栏目:
出版日期:
2020-09-20

文章信息/Info

Title:
Measurement and Correlation of Solid–Liquid Equilibrium
作者:
农韦健 1 胡雪玲 2 陈小鹏 3 韦小凤 2 容建峰 2
(1.广西科开成林科技有限公司,广西 南宁 530022; 2.中国科技开发院广西分院,广西 南宁 530022;3.广西大学化学化工学院,广西 南宁 530004)
关键词:
固-液相平衡测定方法关联模型影响因素
Keywords:
solid-liquid equilibrium measuring method correlation model influencing factors
文献标志码:
A
摘要:
化工生产设计中常涉及蒸发、结晶等固液分离过程。固-液平衡是化工分离的理论基础,固-液平衡数据是设备 结构尺寸设计和操作条件确定的基础数据,因此这些数据及描述它们的数学模型对实现化工生产有重要指导意义。文章着重介 绍固-液相平衡测定方法与特点、详细论述了固-液相平衡影响因素、列举了固-液相平衡数据拟合的数学模型及其应用实例, 为化工结晶分离过程开发提供理论依据。
Abstract:
Solid-liquid separation process such as evaporation, crystallization, often involved in chemical production design. Solid-liquid equilibrium is the theoretical basis of chemical separation. The data of which is the basic data for the design of equipment structure dimensions and the determination of operating conditions.So solid-liquid equilibrium data and the mathematical models described them have important guiding significance for realizing chemical production. Measuring methods, influencing factors, correlation models of solid-liquid equilibrium and their application instances are introduced emphatically in this paper, which can be regarded as theoretical basis for crystallization separation process.

参考文献/References:

[1] 安鑫南. 林产化学工艺学[M]. 北京: 中国林业出版社, 2002: 34, 41. [2] 高艺美,廖晨伊,韦小杰,等. 超声波强化胺盐法单离 枞酸的研究[J]. 高校化学工程学报,2009,23(4): 725-728. [3] Nong W J, Chen X P, Liang J Z et al. Isolation and characterization of abietic acid[J]. Advanced Materials Research, 2014,887-888: 551-556. [4] Yadav J S, Baishya G, Dash U. Synthesis of (+)-amberketal and its analog from l-abietic acid[J]. Tetrahedron, 2007, 63: 9896-9902. [5] Alvarez-Manzaneda E, Chahboun R, Cabrera E, et al. First synthesis of picealactone C. A new route toward taxodionerelated terpenoids from abietic acid[J]. Tetrahedron Letters, 2007, 48(6): 989-992. [6] Li R R, Zhao H K, Jiang S N, et al. Solubility of 1,6-naphthalene disulfonic acid disodium in binary sodium chloride + water, sodium sulfate + water, and ethanol + water solvent mixtures at elevated temperatures[J]. Journal of Chemical & Engineering Data, 2011, 56(5): 2692-2695. [7] Liu Y, Wang J K, Wang X B, et al. Solubility of valsartan in different organic solvents and ethanol + water binary mixtures from (278.15 to 313.15) K[J]. Journal of Chemical & Engineering Data, 2009, 54(3): 986-988. [8] Li D Q, Liu J C, Liu D Z, et al. Solubilities of terephthalaldehydic, p-toluic, benzoic, terephthalic and isophthalic acids in N,N-dimethylformamide from 294.75 to 370.45 K[J]. Fluid Phase Equilibria, 2002, 200(11): 69-74. [9] Carareto N D D, Costa M C, Rolemberg M P, et al. The solid-liquid phase diagrams of binary mixtures of even saturated fatty alcohols[J]. Fluid Phase Equilibria, 2011, 303(2): 191.e1-191.e8. [10] Nong W J, Cheng X P, Wang L L, et al. Measurement and correlation of solid–liquid equilibrium for abietic acid+alcohol systems at atmospheric pressure[J]. Fluid Phase Equilibria, 2014,367: 74-78. [11] Nong W J, Cheng X P, Wang L L, et al. Measurement and correlation of solubility of abietic acid in ethanol+water mixtures[J]. The Journal of Chemical Thermodynamics, 2014,68: 199-204. [12] 王莹. 溶剂效应的量子化学研究[D]. 成都: 四川大学, 2006. [13] 宁左云,聂长明,周凌云,等. 计算机模拟探讨磺胺分 子印迹聚合体系[J]. 南华大学学报(自然科学版),2011, 25(4):97-101. [14] 曲红梅,周立山,杨志才,等. 有机物系固-液相平衡理 论研究评述[J]. 天然气化工,2004,29(6): 57-60. [15] 黎文超,宣爱国,吴元欣,等. 固液平衡的研究进展[J]. 石 油化工,2007,36(10): 1067-1073. [16] 黎文超. 合成碳酸二苯酯相关体系固液平衡研究[D]. 武 汉: 武汉工程大学,2008. [17] Hino T, Prausnitz J M. Solid-liquid equilibria for solutions of binary globular-protein mixtures[J]. AIChE Journal, 1999, 45(3): 622-632. [18] Deng T, Horiuchi S, Roy L E, et al. Solubility of anthracene in ternary 2-butoxyethanol + alkane + propanol solvent mixtures[J]. Journal of Chemical & Engineering Data, 1999, 44(2): 258-261. [19] Peng C, Liu H, Hu Y. Solid–liquid equilibria based on an equation of state for chain fluids[J]. Fluid Phase Equilibria, 2001, 180(1-2): 299-311. [20] Shi X H, Li M, Zhou C R. Measurement and correlation for solubility of 2-chloro-5-chloromethylpyridine in different solvents [J]. Chinese Journal of Chemical Engineering, 2010, 18(4): 654-658. [21] ?lnik L F, Jazbin?k A, Hvala A, et al. Solubility of sodium diclofenac in different solvents[J]. Fluid Phase Equilibria, 2007, 261(1-2): 140-145. [22] González J A, Mozo I, García I, et al. Thermodynamics of 1-alkanol + cyclic ether mixtures[J]. Fluid Phase Equilibria, 2006, 245(2): 168-184. [23] Domańska U, Królikowski M. Phase equilibrium study of the binary systems (N-hexyl-3-methylpyridinium tosylate ionic liquid + water, or organic solvent)[J]. The Journal of Chemical Thermodynamics, 2011, 43(10): 1488-1494. [24] Mao Z, Sun X, Luan X, et al. Measurement and correlation of solubilities of adipic acid in different solvents[J]. Chinese Journal of Chemical Engineering, 2009, 17(3): 473-477. [25] 周彩荣,石晓华,冯伟,等. 新戊二醇在溶剂中溶解度的 测定及关联[J]. 高校化学工程学报,2010,24(3): 365-369. [26] Hu Y H, Chen X, Yang W G, et al. Measurement and correlation of the solubility of 1-(4-methyl-1-naphthyl) ethanone in an aqueous ethanol solution[J]. Fluid Phase Equilibria, 2010, 288(1-2): 83-86. [27] 江燕斌,李凯霞,张扬,等. β-蒿甲醚在五种有机溶剂中 溶解度的测定与关联[J]. 高校化学工程学报,2009, 23(6): 911-915. [28] Luan L J, Zhou Y, Wu Y J, et al. Solubility of scutellarin in methanol, water, ethanol, and ethanol + water binary mixtures from (293.2 to 333.2) K[J]. Journal of Chemical & Engineering Data, 2010, 55(11): 5299-5301. [29] 李殿卿,刘大壮,王福安. 对羧基苯甲醛、对甲基苯甲酸、 苯甲酸、对苯二甲酸和间苯二甲酸在 N,N-二甲基甲酰胺 中的溶解度[J]. 高校化学工程学报,2001,15(3): 258-261.

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备注/Memo

备注/Memo:
【收稿日期】2020-07-10 【基金项目】2018 年度南宁市培养新世纪学术和技术带头人专项资金项目(2018013)。 【作者简介】农韦健(1980-),男,广西科开成林科技有限公司正高级工程师,博士,从事松香松节油等林产化学品 深加工研究工作。
更新日期/Last Update: 2020-11-18